Jpn. J. Appl. Phys. 39 (2000) pp. 1583-1596 |Next Article| |Table of Contents|
|Full Text PDF (693K)| |Buy This Article|
Invited Review Paper
Effects of Discharge Frequency in Plasma Etching and Ultrahigh-Frequency Plasma Source for High-Performance Etching for Ultralarge-Scale Integrated Circuits
Seiji Samukawa,
Vincent M. Donnelly1 and
Mikhail V. Malyshev1
Silicon Systems Research Laboratories, NEC Corporation,
34 Miyukigaoka Tsukuba, Ibaraki 305-8501, Japan
1Bell Laboratories, Lucent Technologies,
600 Mountain Ave. Murray Hill, NJ 07974, USA
(Received January 25, 1999; revised manuscript revised September 1, 1999; accepted for publication January 6, 2000)
A low-temperature, uniform, high-density plasma is produced by applying
ultrahigh-frequency (UHF) power through a spokewise antenna. The plasma is uniform
within ±5% over a diameter of 30 cm. No magnetic field is needed to maintain
the high-density plasma. Consequently, the plasma source is fairly simple and
lightweight. This plasma creates a high electron density and a low degree of
dissociation of the feed gas at the same time because the electron energy distribution
function is not Maxwellian (bi-Maxwellian distributions). The plasma characteristics
are highly suitable for the precise etching of Al and gate electrodes. Additionally, by
the combination of bi-Maxwellian electron energy distribution in the UHF plasma and
new fluorocarbon gas chemistries (C2F4, CF3I), selective radical
generations of CF2 and CF3 could be realized for high-aspect contact hole
patterning of SiO2. A high ion density and a high-energy tail in the electron energy
distribution can also be maintained over a wide range of pressure
(from 3 to 20 mTorr), whereas in conventional inductively coupled plasma
(ICP: 13.56 MHz), the ion density and number of high-energy electrons are drastically
reduced when the gas pressure is increased. This indicates that the ionization in the
UHF plasma does not depend significantly on gas pressures between 3 and 20 mTorr
because the discharge frequency is higher than the frequency of electron collisions in
the plasma. As a result, the UHF plasma provides a process window for
high-performance etching that is wider than the one provided by an ICP.
KEYWORDS:
discharge frequency, ultrahigh-frequency plasma, inductively coupled plasma,
electron energy distribution function, plasma etching
URL:
http://jjap.ipap.jp/link?JJAP/39/1583/
DOI: 10.1143/JJAP.39.1583
- N. Fujiwara, T. Maruyama, M. Yoneda and K. Tsukamoto: Proc. 15 Dry Process Sump. (Institute of Electrical Engineering of Japan, Tokyo, 1993) p. 45.
- T. Nozawa and T. Kinoshita:
Jpn. J. Appl. Phys. 34 (1995) 2107[IPAP].
- H. Ootera:
Jpn. J. Appl. Phys. 33 (1993) 6109[IPAP].
- H. Ohtake and S. Samukawa: Proc. 17 Dry Process Symp. (Institute of Electrical Engineering of Japan, Tokyo, 1995) p. 45.
- S. Samukawa, Y. Nakagawa, T. Tsukada, H. Ueyama and K. Shinohara:
Appl. Phys. Lett. 67 (1995) 1414[AIP Scitation].
- S. Samukawa, Y. Nakagawa, T. Tsukada, H. Ueyama and K. Shinohara:
Jpn. J. Appl. Phys. 34 (1995) 6805[IPAP].
- T. Nakano, H. Ohtake and S. Samukawa:
Jpn. J. Appl. Phys. 35 (1996) L338[IPAP].
- S. Samukawa and T. Nakano:
J. Vac. Sci. & Technol. A 14 (1996) 1002[AIP Scitation].
- S. Samukawa and T. Tsukada:
Appl. Phys. Lett. 69 (1996) 1056[AIP Scitation].
- S. Samukawa and T. Tsukada:
Jpn. J. Appl. Phys. 36 (1997) 7646[IPAP].
- M. V. Malyshev, V. M. Donnelly and S. Samukawa:
J. Appl. Phys. 84 (1998) 1222[AIP Scitation].
- M. V. Malyshev and V. M. Donnelly:
J. Vac. Sci. & Technol. A 15 (1997) 550[AIP Scitation].
- V. M. Donnelly, M. V. Malyshev, A.Kornblit, N. A. Ciampa, J. I. Colonell and J. T. C. Lee:
Jpn. J. Appl. Phys. 37 (1998) 878[IPAP].
- V. M. Donnelly:
J. Vac. Sci. & Technol. A 14 (1996) 1076[AIP Scitation].
- M. V. Malyshev, V. M. Donnelly, A. Kornbilt and N. A. Ciampa:
J. Appl. Phys. 84 (1998) 137[AIP Scitation].
- M. A. Lieberman and A. J. Lichtenberg: Principles of Plasma Discharges and Materials Processing (Wiley, New York, 1994) p. 306.
- V. A. Godyak, R. B. Piejak and B. M. Alexandrovich:
Plasma Sources Sci. Technol. 4 (1995) 332[IoP STACKS].
- A. Schwabedissen, E. C. Bench and J. R. Roberts:
Phys. Rev. E 55 (1997) 3450[APS].
- Y. P. Raizer: Gas Discharge Physics (Springer-Verlag, Berlin, 1991) pp. 37.
- Collision frequencies for electrons with Cl2 and Cl were computed by multiplying the electron velocity by the momentum transfer cross sections computed by Rescigno [rf21] (for Cl2) and Griffin et al.. [rf22] (for Cl), assuming a pressure 10 mTorr for Cl2 and Cl, and a gas temperature of 500 K.
- T. N. Rescigno:
Phys. Rev. A 50 (1994) 1382[APS].
- D. C. Griffin, M. S. Pindzola, T. W. Gorczyca and N. R. Badnell:
Phys. Rev. A 51 (1995) 2265[APS].
- S. Samukawa and H. Akashi: IEEE Trans. Plasma Sci. 26 (1998) 1621.
- D. A. Danner and D. W. Hess:
J. Appl. Phys. 59 (1986) 940[AIP Scitation].
- S. Samukawa:
J. Vac. Sci. & Technol. A 17 (1999) 774[AIP Scitation].
- H. F. Winters and D. Haarer:
Phys. Rev. B 36 (1987) 6613[APS].
- S. Tachi, K. Miyake and T. Tokuyama:
Jpn. J. Appl. Phys. 21 (1982) 141[IPAP].
- T. Sakai, H. Hayashi, J. Abe, K. Horioka and H. Okano: Proc. 15 Dry Process Symp. (Institute of Electrical Engineers of Japan, 1993) p. 193.
- T. Tatsumi, H. Hayashi, S. Morishita, S. Noda, M. Okigawa, N. Itabashi, Y. hikosaka and M. Inoue:
Jpn. J. Appl. Phys. 37 (1998) 2394[IPAP].
- H. Itoh:
J. Phys. D 24 (1991) 277[IoP STACKS].
- S. Samukawa, T. Mukai and K. Tsuda:
J. Vac. Sci. & Technol. A 17 (1999) 2551[AIP Scitation].
- While these are thermodynamic bond strengths, we expect the relative trends to hold for electron impact dissociation thresholds. In addition, we expect the peak cross section energies to follow the same trends, so that those processes with the weakest bond strength will have the largest electron impact dissociation rate constants for the relatively cold bulk electron temperatures in the UHF plasma.
- H. Taoyoda, M. Iio and H. Sugai:
Jpn. J. Appl. Phys. 36 (1997) 3730[IPAP].
- K. Takahashi, M. Hori, K. Maruyama, S. Kishimoto and T. Goto:
Jpn. J. Appl. Phys. 32 (1993) L694[IPAP].
- K. Takahashi, M. Hori and T. Goto:
Jpn. J. Appl. Phys. 32 (1993) L1088[IPAP].
- K. Miyata, K. Takahashi, S. Kishimoto, M. Hori and T. Goto:
Jpn. J. Appl. Phys. 34 (1995) L444[IPAP].
- S. Samukawa and T. Mukai:
to be published in J. Vac. Sci. & Technol. B 18 (2000) 166[AIP Scitation].